electrochemistry – Cabot Institute for the Environment blog

The new carbon economy – transforming waste into a resource

Posted on October 16, 2018April 13, 2023 by janet.crompton

As part of Green Great Britain Week, supported by BEIS, we are posting a series of blogs throughout the week highlighting what work is going on at the University of Bristol’s Cabot Institute for the Environment to help provide up to date climate science, technology and solutions for government and industry. We will also be highlighting some of the big sustainability actions happening across the University and local community in order to do our part to mitigate the negative effects of global warming. Today our blog will look at ‘Technologies of the future: clean growth and innovation’.

On Monday 8 October 2018, the IPCC released a special report which calls upon world governments to enact policies which will limit global warming to 1.5°C compared with pre-industrial levels, failure to do so will drastically increase the probability of ecosystem collapses, extreme weather events and complete melting of Arctic sea ice. Success will require “rapid and far-reaching” actions in the way we live, move, produce and consume.

So, what comes to mind when you hear carbon dioxide – a greenhouse gas? A waste product? You’re not wrong to think that given the predicament that our planet faces, but this article is going to tell the other side of the story which you already know but is often forgotten.

For over a billion years, carbon dioxide has been trapped and transformed, almost miraculously, into an innumerable, rich and complex family of organic molecules and materials by photosynthetic organisms. Without this process, life as we know simply would not have evolved. Look around you, – I dare say that the story of carbon dioxide is weaved, one way or another into all the objects you see around you in this moment. Whether it’s the carbon atoms within the material itself – or that old fossilised sourced of carbon was used to smelt, melt or fabricate it.

The great growth and development of the last two centuries has been defined by humanity’s use of fossilised carbon which drove the first and second industrial revolutions. But now – the limitations of those very revolutions are staring us in the face and a new revolution is already underway, albeit it quietly.

An industrial revolution is said to occur when there is a step change in three forms of technology, Information, Transport and Energy. The step change that I will discuss here is the use of carbon dioxide coupled with renewable energy systems to deliver a circular carbon economy that aims to be sustainable, carbon neutral at worst and carbon negative at best. This burgeoning field comes under the name carbon capture and utilisation (CCU). CCU, represents a broad range of chemical processes that will most directly impact energy storage and generation and the production of chemical commodities including plastics and building aggregates such as limestone.

In our research we are developing catalysts made of metal nanoparticles to activate and react CO2 to form chemicals such as carbon monoxide (CO), formic acid, methanol and acetate. They be simple molecules – but they have significant industrial relevance, are made on vast scales, are energy intensive to produce, and all originate in some way from coal. The methods that we are investigating while being more technically challenging, consume just three inputs – CO2, water and an electrical current. We use a device called an electrolyser, it uses electricity to break chemical bonds and form new ones. The catalyst sits on the electrodes. At the anode, water is broken into positively charged hydrogen ions called protons and oxygen, while at the opposite electrode, the cathode, CO2 reacts with the protons, H+, to form new molecules. It sounds simple but encouraging CO2 to react is not easy, compared to most molecules, CO2 is a stubborn reactant. It needs the right environment and some energy such as heat, electricity or light to activate it to form products of higher energy content. The chemicals that can be produced by this process are industrially significant, they are used in chemical synthesis, as solvents, reactants and many other things. CO for example can be built up to form cleaner burning petroleum/diesel-like fuels, oils, lubricants and other products derived by the petrochemical industry.

Formic acid and methanol may be used to generate energy, they can be oxidised back to CO2 and H2O using a device called a fuel cell to deliver electricity efficiently without combustion. One day we could see electrically driven cars not powered by batteries or compressed hydrogen but by methanol which has a higher volumetric energy density than both batteries and hydrogen. Batteries are heavy, too short-lived and use high quantities of low abundance metals such as lithium and cobalt – meaning their supply chains could suffer critical issues in the future. While the compression of hydrogen is an energy intensive process which poses greater safety challenges.

However, there are still many hurdles to overcome. I recently went to the Joint European Summer School on Fuel Cell, Electrolyser and Battery Technologies. There I learned about the technical and economic challenges from an academic and industrial perspective. In an introductory lecture, Jens Oluf Jensen was asked “When will we run out of fossil fuels?”, his answer “Not soon enough!”. An obvious answer but there is something I wish to unpick. The task for scientists is not just to make technologies like CO2 capture, CO2 conversion and fuel cells practical – which I would argue is already the case for some renewable technological processes. The greatest challenge is to make them cost competitive with their oil-based equivalents. A gamechanger in this field will be the day that politicians enact policies which incorporate the cost to the environment in the price of energy and materials derived from fossil fuels, and even go so far as to subsidise the cost of energy and materials-based on their ability to avoid or trap carbon dioxide.

Even without such political input there is still hope as we’ve seen the cost of solar and wind drop dramatically, lower than some fossil fuel-based power sources and only with limited government support. Already there are companies springing up in the CCU sector. Companies like Climeworks and Carbon Engineering are demonstrating technology that can trap CO2 using a process known as Direct Air Capture (DAC). Carbon Engineering is going even further and developing a technology they call Air to Fuels™. They use CO2 from the air, hydrogen split from water and clean electricity to generate synthetic transportation fuels such as gasoline, diesel or jet fuel. You may question why we should need these fuels given the rise of battery powered vehicles but a better solution for fuelling heavy goods vehicles, cargo ships and long-haul flights is at the very least a decade way.

In 1975, Primo Levi wrote a story about a carbon dioxide molecule and he said in relation to photosynthesis “dear colleagues, when we learn to do likewise we will be sicut Deus [like God], and we will have also solved the problem of hunger in the world.”. The circular carbon economy may still be in its infancy, but the seeds have sprouted. Unlike the first and second industrial revolution, the 3rd industrial revolution will not be dependent on one single energy source but will be a highly interdependent network of technologies that support and complement each other in the aim of sustainability, just like nature itself.

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This blog is written by Cabot Institute member Gaël Gobaille-Shaw, University of Bristol School of Chemistry. He is currently designing new electrocatalysts for the conversion of CO2 to liquid fuels.
For updates on this work, follow @CatalysisCDT @Gael_Gobaille and @UoB_Electrochem on Twitter. Follow #GreenGB for updates on the Green Great Britain Week.

Gael Gobaille-Shaw

Read other blogs in this Green Great Britain Week series:
1. Just the tip of the iceberg: Climate research at the Bristol Glaciology Centre
2. Monitoring greenhouse gas emissions: Now more important than ever?
3. Digital future of renewable energy
4. The new carbon economy – transforming waste into a resource
5. Systems thinking: 5 ways to be a more sustainable university
6. Local students + local communities = action on the local environment

Hydrogen and fuel cells: Innovative solutions for low carbon heat

Posted on March 10, 2016April 12, 2023 by janet.crompton

On 29 February 2016, I attended a meeting in Westminster that was jointly organised by the UK Hydrogen and Fuel Cell Association (UKFCA) and Carbon Connect with the aim of discussing current challenges in the decarbonisation of heat generation in the UK. The panel included David Joffe (Committee on Climate Change), Dr. Marcus Newborough (ITM Power), Ian Chisholm (Doosan Babcock), Klaus Ullrich (Fuel Cell Energy Solutions), Phil Caldwell (Ceres Power) and was chaired by Dr Alan Whitehead MP and Shadow Energy Minister. The attendees included a number of key players in the field of hydrogen production, fuel cell and renewable energy industries, as well as organisations such as the Department for Energy and Climate Change (DECC).

To set the scene, I would like to quote some facts and figures from the 2015 Carbon Connect report on the Future of Heat (part II).

The 2025 carbon reduction target is 404.4 MtCO2e (million metric tons of carbon dioxide equivalent), but the reduction levels as of 2014 have only been 288.9 MtCO2e. The current Government’s low carbon policy framework is woefully inadequate to bridge this gap.
The government introduced the Renewable Heat Incentive in 2011, with the ambition of increasing the contribution of renewable energy source to 12% of the heat demand by 2020. Some of the initiatives include biomass, “energy from waste” and geothermal. However, clear policies and financial incentives are nowhere to be seen.
What is the current situation of renewable heat and how good is the 12% target? The good news is that there is a slight increase in the renewable share from 2004. The really bad news is that the contribution as of 2013 is just 2.6%. The UK is further behind any other EU state with regards to its renewable heat target. Sweden has a whopping 67.2% contribution and Finland 50.9%.

Towards a decarbonised energy sector, two important networks should be considered, electrical and gas. Electrification of heat is very well suited for low carbon heat generation, however, the electricity demands at peak time could be extremely costly. The UK’s gas network is a major infrastructure which is vital for providing gas during peak heat demand. However, it needs to be re-purposed in order to carry low carbon gas such as bio-methane, hydrogen or synthetic natural gas.

It was clear from the debate that hydrogen can play an important role in decreasing carbon emissions even within the current gas network. The introduction of up to 10% of hydrogen into gas feed can still be compatible with current gas networks and modern appliances, while generating a significant carbon emission reduction. However, where is the hydrogen coming from? For heat production at the national scale, steam reforming is the only player. However, with the government pulling away from carbon capture and storage (CCS), this option cannot provide a significant reduction in carbon emissions. Capital costs associated with electrolysers would not be able to deliver the amount of hydrogen required at peak demands. The frustration in this community with regards to the future of CCS was palpable during the networking session.

We need hydrogen, generated from renewable energy sources… but the question is how?

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This blog is written by Cabot Institute member David J. Fermin, Professor of Electrochemistry in the University of Bristol’s School of Chemistry. His research group are currently looking at the direct conversion of solar energy to chemical fuels, in particular hydrogen; the conversion of CO2 to fuels; and electrocatalysts for energy vectors (e.g. what you put in fuel cells and electrolysers).

David Fermin

David will be giving a free talk on the challenges of solar energy conversion and storage on Tuesday 12 April 2016 at 6.15 pm at the University of Bristol. To find out more and to book your ticket, visit the University of Bristol’s Public and Ceremonial Events web page.

Materials and energy… over a pint?

Posted on May 30, 2014April 14, 2023 by janet.crompton

Bristol, along with 20 other cities, in 6 different countries, was host to an interesting approach to science communication – over three nights, 19 – 21 May 2014, science took place at the pub!

Although varied, relevant and interesting research takes place every day at Universities, in many cases the general public is completely unaware of what goes on inside them – other than lectures and exams! Pint of Science is a volunteer-based, not-for-profit festival, which takes academic research into the everyday world, by having scientists at the pub sharing their work and answering questions.

Premièring this year in Bristol, the festival was well received, with many of the events sold-out before the doors were even opened. Across the city, four pubs opened their doors to a curious audience looking to learn about a range of topics from nanotechnology, to energy, to the brain and oceans or volcanoes.

Engaging society being at the heart of the Cabot Institute’s aims, it was quick to become involved when approached. As well as sponsoring the event, the Institute was well represented by two of its members, Professors David Fermín and Paul Weaver, who shared their research during the festival.

Energy, Materials and the Electrochemist Dream

L-R David Parker and David Fermin

Prof David Fermín and one of his PhD students, Mr David Parker, took on the second evening of the festival, talking about “Energy, Materials and the Electrochemist Dream”. During this event renewable energy sources, in particular solar, were championed. Of interest was the many ways in which solar energy can be harvested and used, whether to be directly converted into electricity or used to produce “solar fuels” from water or carbon dioxide. The need for developing new photovoltaic materials, which are cheap, efficient and made from abundant elements, was stressed. Questions from the public revolved about “how green” these technologies really are and the need to develop a “complete, systematic” approach to energy, which can incorporate various forms and sources of energy. This last is another key interest of the Institute, with groups in Bristol doing interesting work in this area.

Morphing cars, planes and wind turbines: the shape of things to come

Paul Weaver talks to the pub-goers

On the festival’s last evening, Prof Paul Weaver and one of his PhD students, Eric Eckstein, talked about “Morphing cars, planes and wind turbines: the shape of things to come”. They discussed the development of new composite materials with the ability to tailor structural properties and the difficulties involved in predicting responses. Also highlighted was the very important interaction and synergy between University and Industry in this field. In a particularly interactive approach they brought along many of the composite materials they work with, alongside demonstrating the strength and failure of various materials, allowing the public to see and feel how different properties can be altered. The use of composite materials in wind turbines and helicopter blades was of particular interest and generated an animated discussion on the subject.

This blog was written by Cabot Institute members Daniela Plana (Chemistry) and Matt Such (ACCIS) at the University of Bristol.